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(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine

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Formula: C36H30NO2P
CAS: 380230-02-4
search Element: phosphacyclohepta dinaphthalen phenylethyl amine dioxa
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Identification

Structural Formula
(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
CAS:
380230-02-4
EINECS:
Molecular Formula:
C36H30NO2P
MDL:
SMILES:
C[C@H](N([C@@H](C)C1=CC=CC=C1)P1OC2=CC=C3C=CC=CC3=C2C2=C(O1)C=CC1=CC=CC=C21)C1=CC=CC=C1
Synonym:
(+)-n,n-bis[(1s)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, (11br) ; n,n-bis((s)-1-phenylethyl)dinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine ; (s,s,s)-(+)-(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine ; (s)-(+)-(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1s)-1-phenylethyl]amine ; 3,4-a']dinaphthalen-4-yl)bis[(1s)-1-phenylethyl]amine,min.95% ; n,n-bis[(1s)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine ; 3,4-a']dinaphthalen-4-yl)bis[(1s)-1-phenylethyl]amine ; 3,4-a']dinaphthalen-4-yl)bis[(1s)-1-phenylethyl]amine,95% ; 3,4-a']dinaphthalen-4-yl)bis[(1s)-1-phenylethyl]amine, min. 95% ; (s,s,s)-(+)-(3,5-dioxa-4-phospha-cyclohe


Description

Used in a palladium-catalyzed diethylzinc mediated umpolung allylation. Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors.


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Santa Cruz Biotechnology, Inc.
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Properties for (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine

Molecular Weight:
539.6 g·mol−1
Melting point:
88-89 °C
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Safety & Transport Information

Risk Codes:
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
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Alternative Distributors of [(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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