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(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine

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Formula: C37H32Cl2NO2P
CAS: 415918-91-1
search Element: phosphacyclohepta dinaphthalen phenylethyl amine dioxa
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Identification

Structural Formula
(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
CAS:
415918-91-1
EINECS:
Molecular Formula:
C37H32Cl2NO2P
MDL:
MFCD04117687
SMILES:
C[C@H](C1=CC=CC=C1)N([C@H](C)C2=CC=CC=C2)P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76
Synonym:
(r)-2,2-binaphthoyl-(s,s)-di(1-phenylethyl)aminoylphosphine ; 3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine ; 3,4-a']dinaphthalen-4-yl)bis[(1r)-1-phenylethyl]amine ; (s,r,r)-(+)-(3,5-dioxa-4-phospha-cyclohe ; 3,4-a']dinaphthalen-4-yl)bis[(1r)-1-phenylethyl]amine, dichloromethane adduct, min. 95% ; 3,4-a']dinaphthalen-4-yl)bis[(1r)-1-phenylethyl]amine,dichloromethaneadduct,min.95% ; r-(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1r)-1-phenylethyl]amine ; (s,r,r)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a ; 3,4-a']dinaphthalen-4-yl)bis[(1r)-1-phenylethyl]amine, dichloromethane adduct,95% ; 3,4-a']dinaphthalen-4-yl)bis[(1r)-1-phenylethyl]amine, dichloromethane adduct


Description

Used in a palladium-catalyzed diethylzinc mediated umpolung allylation. Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors.


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Santa Cruz Biotechnology, Inc.
253450
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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
Chemieliva Pharmaceutical Co., Ltd.
CP68320204960

Prices & Availability




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Properties for (S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine

Molecular Weight:
624.54 g·mol−1
Melting point:
102-103 °C
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
Hazard Symbols:
Xn
Hazard symbol Xn
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Alternative Distributors of [(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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