Diisobutylaluminum hydride; 20% (ca. 1M) solution in toluene | CAS 1191-15-7

Element: diisobutylaluminum solution hydride toluene

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C-S » Chemicals » diisobutylaluminum-hydride-solution-toluene-PX1889264

Identification

Diisobutylaluminum hydride; 20% (ca. 1M) solution in toluene

CAS:

1191-15-7

EINECS:

214-729-9

Molecular Formula:

C₈H₁₉Al

MDL:

MFCD00008928

Synonym:

diisobutylaluminum ; al-alchili ; dibah ; dibah~dibal-h ; al-diisobutyl ; 1m in dcm ; dibal (1n in hexane) ; dibal-h ; dibal ; bisisobutylaluminum

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Prices & Availability

Data is processed

Properties for Diisobutylaluminum hydride; 20% (ca. 1M) solution in toluene

Molecular Weight:

142.22 g·mol−1

Density:

1.23 g/mL at 25 °C

Melting point:

-70 °C

Boiling point:

65 °C

Flash point:

40 ºF

Physical Description:

clear solution

Hazard Statements

GHS02
Flammable

Flammable gases, category 1
Flammable aerosols, categories 1, 2
Flammable liquids, categories 1, 2, 3
Flammable solids, categories 1, 2
Self-reactive substances and mixtures, types B, C, D, E, F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Combustible solids, category 3
Combustible liquids, category 3
Self-heating substances and mixtures, categories 1, 2
Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
Organic peroxides, types B, C, D, E, F

GHS05
Corrosive

Corrosive to metals, category 1

GHS03
Harmful

Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, categories 2, 3
Eye irritation, category 2A
Skin sensitization, category 1
Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects

Not used

with the "skull and crossbones" pictogram
for skin or eye irritation if:
the "corrosion" pictogram also appears
the "health hazard" pictogram is used to indicate respiratory sensitization

GHS08
Health hazard

Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A, 1B, 2
Carcinogenicity, categories 1A, 1B, 2
Reproductive toxicity, categories 1A, 1B, 2
Specific target organ toxicity following single exposure, categories 1, 2
Specific target organ toxicity following repeated exposure, categories 1, 2
Aspiration hazard, categories 1, 2

GHS09
Environmental hazard

Acute hazards to the aquatic environment, category 1
Chronic hazards to the aquatic environment, categories 1, 2
Environmental toxicity, categories 1, 2

Safety & Transport Information

Risk Codes:

R11 - Highly flammable
R14 - Reacts violently with water
R14/15 - Reacts violently with water, liberating extremely flammable gases
R15 - Contact with water liberates extremely flammable gases
R17 - Spontaneously flammable in air
R19 - May form explosive peroxides
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed
R22 - Harmful if swallowed
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed
R34 - Causes burns
R35 - Causes severe burns
R37 - Irritating to respiratory system
R40 - Limited evidence of a carcinogenic effect
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 - Possible risk of impaired fertility
R63 - Possible risk of harm to the unborn child
R65 - Harmful: may cause lung damage if swallowed
R67 - Vapours may cause drowsiness and dizziness

Safety Codes:

S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27 - Take off immediately all contaminated clothing
S29 - Do not empty into drains
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S46 - If swallowed, seek medical advice immediately and show this container or label
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S9 - Keep container in a well-ventilated place

Hazard Classes:

4.3

Hazard Symbols:

F, T, C, N
Hazard symbol T

Storage temperature :

2-8°C

RID/ADR certification :

UN 3399 4.3 / PG 1

Alternative Distributors of [Diisobutylaluminum hydride; 20% (ca. 1M) solution in toluene]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG | Pfaltz & Bauer, Inc.

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