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Diisobutylaluminum hydride, 1M solution in toluene

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Formula: C8H19Al
CAS: 1191-15-7
search Element: diisobutylaluminum solution hydride toluene
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Identification

Structural Formula
Diisobutylaluminum hydride, 1M solution in toluene
CAS:
1191-15-7
EINECS:
214-729-9
Molecular Formula:
C8H19Al
MDL:
MFCD00008928
Synonym:
diisobutylaluminum ; al-alchili ; dibah ; dibah~dibal-h ; al-diisobutyl ; 1m in dcm ; dibal (1n in hexane) ; dibal-h ; dibal ; bisisobutylaluminum




Suppliers

Alfa (A Johnson Matthey Company)
A960028800
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Prices & Availability




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Properties for Diisobutylaluminum hydride, 1M solution in toluene

Molecular Weight:
142.22 g·mol−1
Density:
1.23 g/mL at 25 °C
Melting point:
-70 °C
Boiling point:
65 °C
Flash point:
40 ºF
Physical Description:
clear solution
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2
GHS09

GHS09
Environmental hazard
  • Acute hazards to the aquatic environment, category 1
  • Chronic hazards to the aquatic environment, categories 1, 2
  • Environmental toxicity, categories 1, 2

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R14 - Reacts violently with water
R14/15 - Reacts violently with water, liberating extremely flammable gases
R15 - Contact with water liberates extremely flammable gases
R17 - Spontaneously flammable in air
R19 - May form explosive peroxides
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed
R22 - Harmful if swallowed
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed
R34 - Causes burns
R35 - Causes severe burns
R37 - Irritating to respiratory system
R40 - Limited evidence of a carcinogenic effect
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 - Possible risk of impaired fertility
R63 - Possible risk of harm to the unborn child
R65 - Harmful: may cause lung damage if swallowed
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27 - Take off immediately all contaminated clothing
S29 - Do not empty into drains
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S46 - If swallowed, seek medical advice immediately and show this container or label
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S9 - Keep container in a well-ventilated place
Hazard Classes:
4.3
Hazard Symbols:
F, T, C, N
Hazard symbol T Hazard symbol C Hazard symbol N Hazard symbol F
Storage temperature :
2-8°C
RID/ADR certification :
UN 3399 4.3 / PG 1
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Alternative Distributors of [Diisobutylaluminum hydride, 1M solution in toluene]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG | Pfaltz & Bauer, Inc.

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Downloads

Mol File:
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MSDS:
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