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(R)-C3-TunePhos

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Formula: C39H32 O2 P2
CAS: 301847-89-2
search Element: tunephos
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Identification

Structural Formula
(R)-C3-TunePhos
CAS:
301847-89-2
EINECS:
Molecular Formula:
C39H32 O2 P2
MDL:
MFCD06658115
SMILES:
C1COC2=CC=CC(P(C3=CC=CC=C3)C3=CC=CC=C3)=C2C2=C(OC1)C=CC=C2P(C1=CC=CC=C1)C1=CC=CC=C1
Synonym:
r-(-)-1,13-bis(diphenylphosphino)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin (r)-c3-tunephos ; (r)-(6,6'-o-(1,3-propylene)-oxylbiphenyl-2,2'-diyl)bis(diphenyl)phosphine ; phosphine,1,1'-[(13ar)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl- ; (r)-c3-tunaphos ; (r)-c3-tunephos ; (s)-c3-tunephos ; (s)-(+)-1,13-bis(diphenylphosphino)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin ; phosphine,[(13ar)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[diphenyl- (9ci) ; r-(-)-1,13-bis(diphenylphosphino)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin,97%(r)-c3-tunephos ; r-(-)-1,13-bis(diphenylphosphino)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin


Description

This provides comparable or superior enantioselectivities and catalytic abilities to BINAP in Ru-catalyzed asymmetric hydrogenations of β-keto esters, cyclic β-(acylamino)acrylates and α-phthalimide ketones.


Suppliers

Santa Cruz Biotechnology, Inc.
255516
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Prices & Availability




Data is processed


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Properties for (R)-C3-TunePhos

Molecular Weight:
594.62 g·mol−1
Melting point:
153-161 °C(lit.)
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

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Alternative Distributors of [(R)-C3-TunePhos]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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Downloads

Mol File:
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MSDS:
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