(R)-TRIP | CAS 791616-63-2 | Chemical-Suppliers

Element: trip

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C-S » Chemicals » trip-PX52595

Identification

(R)-TRIP

CAS:

791616-63-2

EINECS:

Molecular Formula:

C₅₀H₅₇ O₄ P

MDL:

MFCD10567009

SMILES:

CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=C(C=C(C=C7C(C)C)C(C)C)C(C)C)O)C(C)C

Synonym:

dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin,4-hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-, 4-oxide, (11br)- ; (r)-3,3'-bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate ; (s)-3,3'-bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate ; (r)-3,3'-bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate ; (11br)-4-hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide ; (r)-trip, (11br)-4-hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1',2'-f]-1,3,2-dioxaphosphepin 4-oxide, (r)-3,3'-bis(2,4,6-triisopropylphenyl)-1,1'-bi-2-naphthol cyclic monophosphate ; (r)-trip ; (r)-3,3'-bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate ; (r)-trip, (11br)-4-hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1',2'-f]-1,3,2-dioxaphosphepin 4-oxide, (r)-3,3'-bis(2,4,6-triisopropylphenyl)-1,1'-bi-2-naphthol cyclic monophosphate ; (s)-3,3'-bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate ; (r)-3,3'-bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate >=97.5% (hplc)

Description

(R)-TRIP, short for 3,3'-bis(2,4,6-triisopropylphenyl)-2,2'-binaphtholate, is a chiral phosphonic acid derived from BINOL. (R)-TRIP has been described as a ligand in the preparation of a Mo-based complex for chiral olefin metathesis catalysis. (R)-TRIP has also been used as a chiral Bronsted acid in an enantioselective cascade reaction to generate pharmaceutically relevant 3-substituted cyclohexylamines. (S)-TRIP is also available.

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