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(Trimethylsilyl)methylmagnesium chloride solution

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Formula: (CH3)3SiCH2MgCl
CAS: 13170-43-9
search Element: methylmagnesium trimethylsilyl chloride solution
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Identification

Structural Formula
(Trimethylsilyl)methylmagnesium chloride solution
CAS:
13170-43-9
EINECS:
Molecular Formula:
(CH3)3SiCH2MgCl
MDL:
MFCD00009916
SMILES:
C[Si](C)(C)[CH2-].[Mg+2].[Cl-]
Synonym:
(trimethylsilyl)methylmagnesium chloride, 0.5m in 2-methf ; (trimethylsilyl)methylmagnesium chloride solution ; (20% in ethyl ether, ca. 1mol/l) ; (trimethylsilylmethyl)chloromagnesium ; trimethylsilylmethylchloromagnesium ; trimethylsilylmethylmagnesium chloride ; trimethylsilylmethylmagnesium chloride  ; (trimethylsilyl)methylmagnesium chl. sol ; trimethylsiylmethylmagnesium chloride ; trimethylsilylmethyl


Description

(Trimethylsilyl)methylmagnesium chloride solution is a reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.


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Santa Cruz Biotechnology, Inc.
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Prices & Availability




Data is processed


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Properties for (Trimethylsilyl)methylmagnesium chloride solution

Molecular Weight:
146.97 g·mol−1
Density:
1.04
Flash point:
-40 °C
Physical Description:
grey liquid
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R12 - Extremely flammable
R14 - Reacts violently with water
R19 - May form explosive peroxides
R22 - Harmful if swallowed
R34 - Causes burns
R66 - Repeated exposure may cause skin dryness or cracking
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
Hazard Classes:
8
Hazard Symbols:
F+, C, F
Hazard symbol C Hazard symbol F+ Hazard symbol F
Storage temperature :
Flammables + water-Freezer (-20 °C)e area
RID/ADR certification :
UN 3399 4.3 / PG 1
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Alternative Distributors of [(Trimethylsilyl)methylmagnesium chloride solution]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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Downloads

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MSDS:
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