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2-(Trimethylsilyl)ethoxymethyl chloride

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Formula: C6H15ClOSi
CAS: 76513-69-4

Identification

Structural Formula
2-(Trimethylsilyl)ethoxymethyl chloride
CAS:
76513-69-4
EINECS:
278-483-4
Molecular Formula:
C6H15ClOSi
MDL:
MFCD00009919
SMILES:
C[Si](C)(C)CCOCCl
Synonym:
2-(trimethysilyl)-ethoxymethyl chloride ; 2-chloroethoxymethyltrimethylsilane ; 2-(trimethylsilyl)ethoxymethyl chl ; 2-(trimethylsilyl)ethoxymethyl chloride ; sem-ci ; sem-cl ; sem-chloride ; 2-(trimethsilyl)-ethoxymethyl chloride ; 2-(chloromethoxy)ethyltrimethylsilane ; -(trimethysilyl)-ethoxymethylchloride


Description

This is used to prepare a SEM-ether which, removed with BBr3 and cyclized to a benzo-oxapane. Phenol protecting group in the synthesis of laterifluorones.


Suppliers

Nantong Xindao Biotech Ltd
NXB405616224
BLD Pharmatech Ltd
BP28088424
Chemlyte Solutions
CS28088424
FUDI Chemical Co. Ltd.
FCC343213728
Norchim S.A.S.
NS21846552
Hangzhou Cherry Pharmaceutical Technology Co., Ltd.
HCPT795639780
Shanghai Ruiyi Medical Tech Co.,Ltd
SRMTC546032760
Hangzhou Keying Chem Co., Ltd.
HKC468018720
Finetech Industry Limited
FIL390015600
Carbone Scientific Co., Ltd.
CS436813104
Xiamen Hisunny Chemical Co., Ltd.
XHC514820592
AK Scientific, Inc.
AS29648892
Capot Chemical Co., Ltd.
7073
Zehao Industry Co., Ltd.
ZI374411232
Amadis Chemical Company Limited
ACCL483624180
Santa Cruz Biotechnology, Inc.
251682
Dayang Chem (Hangzhou) Co.,Ltd.
DC483619344
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CAS equal suppliers

SEMCl
Hangzhou Cherry Pharmaceutical Technology Co., Ltd.
HCPT2551275
2-(Trimethylsilyl)ethoxymethylchloride
Huateng Pharmaceutical Co.,Ltd
98411
Silane, [2-(chloromethoxy)ethyl]trimethyl-
Angene International Limited
AGN-PC-0KK07X
2-Chloromethyl 2-(trimethylsilyl)ethyl ether
Simagchem Corporation
SC462013860
2-chloroMethyl 2-(triMethylsilyl)ethyl ether
Zhejiang Hongxin Chemical
ZHC550022000
2-Chloromethyl 2-(trimethylsilyl)ethyl ether
Autech Industry Co.,Limited
AIC594023760
2-Chloromethyl 2-(trimethylsilyl)ethyl ether
Xiamen Equation Chemical Co.,Ltd
XECC704035200
2-Chloromethyl 2-(trimethylsilyl)ethyl ether
Hangzhou Verychem Science & Technology Co., Ltd.
HVST1056052800
2-Chloromethyl 2-(trimethylsilyl)ethyl ether
Shandong SanYoung Industry Co., Ltd
SSI770030800
2-(Trimethylsilyl)ethoxymethyl Chloride (SEM-Cl)
Ambeed, Inc.
A227867
2-(Trimethylsilyl)ethoxymethyl Chloride, 90%, Technical
Acros Organics BVBA
AOB522520900
2-(Chloromethoxy)ethyltrimethylsilane (stabilized with Diisopropylethylamine)
TCI Chemicals (India) Pvt. Ltd.
C1339
2-(Chloromethoxy)ethyltrimethylsilane, tech. 90%, stab. with 0.3% N-ethyldiisopropylamine
Alfa (A Johnson Matthey Company)
A1993659808
2-(Trimethylsilyl)ethoxymethyl chloride, tech. 90%, stab. with 0.1% N,N-Diisopropylethylamine
Austin Chemical Company, Inc.
ACC2427397092
2-(Trimethylsilyl)ethoxymethyl chloride, tech. 90%, stab. with 0.1% N,N-Diisopropylethylamine
Fox Chemicals GmbH
FC1506645198
2-(Trimethylsilyl)ethoxymethyl chloride, tech. 90%, stab. with 0.1% N,N-Diisopropylethylamine
Chemieliva Pharmaceutical Co., Ltd.
CP2929587885
2-(Trimethylsilyl)ethoxymethyl chloride, tech. 90%, stab. with 0.1% N,N-Diisopropylethylamine
Leap Chem Co., Ltd
LC1506645198
2-(Trimethylsilyl)ethoxymethyl chloride, tech. 90%, stab. with 0.1% N,N-Diisopropylethylamine
Daming Changda Co., Ltd.
LLB00701
2-(Trimethylsilyl)ethoxymethyl chloride, tech. 90%, stab. with 0.1% N,N-Diisopropylethylamine
Quzhou Rundong Chemical Co., Ltd.
QRC27621110484
2-(Trimethylsilyl)ethoxymethyl chloride, tech. 90%, stab. with 0.1% N,N-Diisopropylethylamine
Pharmacore Co., Limited
PL1925157753

Prices & Availability




Data is processed


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Properties for 2-(Trimethylsilyl)ethoxymethyl chloride

Molecular Weight:
166.72 g·mol−1
Density:
0.942 g/mL at 25 °C(lit.)
Boiling point:
170-172 °C(lit.)
Flash point:
116 ºF
Solubility:
Soluble in water (decomposes).
Physical Description:
colorless to light yellow liqui
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1

Safety & Transport Information

Risk Codes:
R10 - Flammable
R34 - Causes burns
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S28 - After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
Hazard Classes:
3.2
Hazard Symbols:
C
Hazard symbol C
Storage temperature :
-20°C
RID/ADR certification :
UN 2920 8 / PG 2
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Alternative Distributors of [2-(Trimethylsilyl)ethoxymethyl chloride]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG | Jinan Great Chemical Co., Ltd. | Pharmasi Chemicals Co., Ltd. | Shanghai Synica Corporation Ltd. | Nanjing Biorgchem Co., Ltd. | Chengdu Qiaofeng Technological Development Co., Ltd. | Shanghai AOKChem Group Limited | Suzhou Rovathin Pharmatech Co., Ltd | Chemrio International Limited | ChengDu KaiXin Technology Development Co., Ltd. | Atomole Scientific Co., Ltd. | Ruiyi Medical Co., Ltd. | Wuxi Mizat Chemical Technology Co., Ltd. | AOKBIO Co., Ltd. | 3Way Pharm Inc. | Kairer Chengdu Pharmaceutical Co., Ltd. | Nanjing Habo Medical Technology Co., Ltd. | Gihi Chemicals Co., Limited | Watson International Ltd | Shanghai Trinity Import & Export Co., Ltd. | BOC Sciences | Shanghai Arbor Chemical Co., Ltd. | Finetech Industry Limited | Jinan Haohua Industry Co., Ltd. | Mascot I.E. Co., Ltd. | Suzhou Vosun Chemical Co.,Ltd. | Sino Rarechem Labs Co. Ltd. | Green Fine Chemical (Shanghai) Co., Ltd.

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