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Trimethyl(trifluoromethyl)silane solution

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Formula: C4H9F3Si
CAS: 81290-20-2
search Element: trifluoromethyl trimethyl solution silane
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Identification

Structural Formula
Trimethyl(trifluoromethyl)silane solution
CAS:
81290-20-2
EINECS:
Molecular Formula:
C4H9F3Si
MDL:
MFCD00145454
SMILES:
C[Si](C)(C)C(F)(F)F
Synonym:
ruppertreagent ; ruppert's reagent ; reagents, ruppert's ; tms-cf3 ; tfmtms ; ruppert's reagent tms-cf3 ; ruppert-prakash reagent ; ttms ; ruppert's ; rupper reagent


Description

Nucleophilic addition of the trifluoromethyl group to ketones and aldehydes.


Suppliers

Santa Cruz Biotechnology, Inc.
253762
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Prices & Availability




Data is processed


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Properties for Trimethyl(trifluoromethyl)silane solution

Molecular Weight:
142.19 g·mol−1
Density:
0.962 g/mL at 20 °C(lit.)
Melting point:
54-55°C
Boiling point:
54-55 °C(lit.)
Flash point:
14 ºF
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R14 - Reacts violently with water
R19 - May form explosive peroxides
R22 - Harmful if swallowed
R36/37 - Irritating to eyes and respiratory system
R36/37/38 - Irritating to eyes, respiratory system and skin
R40 - Limited evidence of a carcinogenic effect
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S29 - Do not empty into drains
S33 - Take precautionary measures against static discharges
S36 - Wear suitable protective clothing
S36/37 - Wear suitable protective clothing and gloves
S39 - Wear eye/face protection
Hazard Classes:
3
Hazard Symbols:
F, Xi, Xn
Hazard symbol F Hazard symbol Xn Hazard symbol Xi
Storage temperature :
2-8°C
RID/ADR certification :
UN 1993 3 / PG 2
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Alternative Distributors of [Trimethyl(trifluoromethyl)silane solution]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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