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4-(Trifluoromethyl)phenylboronic acid

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Formula: C7H6BF3O2
CAS: 128796-39-4

Identification

Structural Formula
4-(Trifluoromethyl)phenylboronic acid
CAS:
128796-39-4
EINECS:
Molecular Formula:
C7H6BF3O2
MDL:
MFCD00151855
Synonym:
4-trifluoromethylphe ; 4-(trifluoromethyl)phenylboric acid ; 4-(trifluuoromethyl)phenylboronicacid ; 4-tirfluromethylphenyl boronic acid ; akos brn-0049 ; 4-boronobenzotrifluoride ; p-(trifluoromethyl)phenylboronic acid ; 4-trifluoromethylboronic acid ; α,α,α-trifluoro-p-tolylboronic acid ; rarechem ah pb 0095


Description

Undergoes direct cross-coupling with allyl alcohols. Used to N-arylate imidazoles and amines with copper-exchanged fluorapatite. Also employed in a microwave-promoted cross-coupling with acid chlorides leading to aryl ketones. Contains varying amounts of anhydride.


Suppliers

Chemlyte Solutions
CS26647992
Shandong Lanhai Industry Co.,Ltd.
SLIC488424420
Allfluoro Pharmaceutical Co. Ltd.
APC488419536
Xiamen Equation Chemical Co.,Ltd
XECC473623680
Hangzhou Ocean Chemical Co., Ltd.
HOC488419536
Simagchem Corporation
SC31089324
Capot Chemical Co., Ltd.
1793
Santa Cruz Biotechnology, Inc.
252107
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CAS equal suppliers

4-Trifluoromethylboronic acid
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Beijing Pure Chem. Co., Ltd.
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Neostar United Industrial Co., Ltd.
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Haihang Industry Co., Ltd.
HI15084524
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Quzhou Rundong Chemical Co., Ltd.
QRC19147656
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Molekula
20407599
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DSL Chemicals (Shanghai) Co., Ltd.
C013728
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Hangzhou Ocean Chemical Co., Ltd.
HOC23109240
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Chemieliva Pharmaceutical Co., Ltd.
CP24507350
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Leap Chem Co., Ltd
LC12603780
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Hangzhou J&H Chemical Co., Ltd.
HJC21708680
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Hefei Hirisun Pharmatech Co., Ltd
HR090019
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Hangzhou Zhongqi Chem Co., Ltd
HZC21008400
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Haihang Industry Co., Ltd.
HI18205460
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Hangzhou Lingrui Chemical Co., Ltd.
HLC24509800
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Wanko Chemical Co., Ltd.
WC16805040
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Ascender Chemical Co.,Ltd
ACC17507000
4-(TRIFLUOROMETHYL)PHENYLBORONICACID
Huateng Pharmaceutical Co.,Ltd
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Celeste Life Sciences Pvt. Ltd.
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Indofine Chemical Co, Inc.
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CM Fine Chemicals
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Shanghai UCHEM Inc.
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Allessa GmbH
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Dayang Chem (Hangzhou) Co.,Ltd.
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Celeste Life Sciences Pvt. Ltd.
CLSP471223560
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DSL Chemicals (Shanghai) Co., Ltd.
DC516820672
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Autech Industry Co.,Limited
AIC410416416
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AK Scientific, Inc.
AS28888664
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Hangzhou Ocean Chemical Co., Ltd.
HOC501620064
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scienTEST - bioKEMIX GmbH
S-B380015200
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Suzhou Vosun Biotech Co.,Ltd
SVBC425621280
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FUDI Chemical Co. Ltd.
FCC334413376
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Xingrui Industry Co., Limited
XIL440817632
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Gihi Chemicals Co., Limited
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H&Z Industry Co.,Ltd
HIC304012160
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Xiamen Hisunny Chemical Co., Ltd.
XHC501620064
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Conscientia Industrial Co., Ltd (Zhejiang Conscientia Pharmaceutical)
CI1048841952
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Changzhou Union Chemicals Co.,Ltd.
CUCC516825840
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Hangzhou Keying Chem Co., Ltd.
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Finetech Industry Limited
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BLD Pharmatech Ltd
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Hangzhou MolCore BioPharmatech Co.,Ltd.
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Ambeed, Inc.
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Acros Organics BVBA
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Angene International Limited
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Alfa (A Johnson Matthey Company)
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TCI Chemicals (India) Pvt. Ltd.
T1788

Prices & Availability




Data is processed


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Properties for 4-(Trifluoromethyl)phenylboronic acid

Molecular Weight:
189.93 g·mol−1
Melting point:
245-250 °C(lit.)
x

Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36 - Wear suitable protective clothing
S37/39 - Wear suitable gloves and eye/face protection
Hazard Classes:
irritant
Hazard Symbols:
Xi, Xn
Hazard symbol Xn Hazard symbol Xi
Storage temperature :
0-6°C
x

Alternative Distributors of [4-(Trifluoromethyl)phenylboronic acid]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

HuaiBei SanHe Developing Co., Ltd. | 3B Scientific Corporation | Hongda Group Limited | Shanghai Inno-trans Chemical Co., Ltd. | ABCR GmbH & Co. KG | Pharmasi Chemicals Co., Ltd. | TCI Europe NV | Chemrio International Limited | Syntechem Co., Ltd. | Shijiazhuang Yiju Pharmaceutical Co., Ltd. | Shanghai Jinglan Chemical Co., Ltd. | Long Island Pharmaceutical & Chemical Co. Ltd. | Chengdu Qiaofeng Technological Development Co., Ltd. | Bona Chemical Co., Limited | Ark Pharm, Inc. | Matrix Scientific | Ruiyuan Group Limited | Wuxi Mizat Chemical Technology Co., Ltd. | Bepharm Ltd. | Hangzhou Pharma & Chem Co. Ltd. | Shijiazhuang JuSha Imp.& Exp. Co.Ltd | Chongqing Share Chemicals Co., Ltd. | Nantong Qihai Chemicals Co., Ltd. | Suzhou Rovathin Pharmatech Co., Ltd | 3Way Pharm Inc. | Kairer Chengdu Pharmaceutical Co., Ltd. | Pangea Chemicals | Jinan Haohua Industry Co., Ltd. | Finetech Industry Limited | Sino Rarechem Labs Co. Ltd. | Beijing Wisdom Chemicals Co., Ltd

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