tert-Butyllithium, nominally 1.5M in n-pentane | CAS 594-19-4

Element: butyllithium nominally pentane tert

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Identification

tert-Butyllithium, nominally 1.5M in n-pentane

CAS:

594-19-4

EINECS:

209-831-5

Molecular Formula:

C₄H₉Li

MDL:

MFCD00008795

Synonym:

1,1-dimethyl-ethane-lithium ; tert-butyllithium solution ; (1,1-dimethylethyl)lithium ; t-butyllithium ; t-buli ; nominally1.5minn-pentane ; lithium tert-butyl ; (1,1-dimethylethyl)-lithium ; (1,1-dimethylethyl)-lithiu ; tert-butyllithium

Suppliers

Alfa (A Johnson Matthey Company)

A736022080

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Shandong SanYoung Industry Co., Ltd

SSI12605040

Lithium, (1,1-dimethylethyl)-

Angene International Limited

AGN-PC-0OCWFC

tert-Butyllithium (solution 15% in n-pentane)

Merck Schuchardt OHG

MSO360014400

tert-Butyllithium, nominally 1.5M in n-pentane, packaged under Argon in resealable ChemSeal bottles

Alfa (A Johnson Matthey Company)

A38016114048

Prices & Availability

Data is processed

Properties for tert-Butyllithium, nominally 1.5M in n-pentane

Molecular Weight:

64.06 g·mol−1

Density:

0.69 g/mL at 20 °C

Boiling point:

36-40 °C

Flash point:

20 ºF

Physical Description:

colourless to pale yellow solution

Hazard Statements

GHS02
Flammable

Flammable gases, category 1
Flammable aerosols, categories 1, 2
Flammable liquids, categories 1, 2, 3
Flammable solids, categories 1, 2
Self-reactive substances and mixtures, types B, C, D, E, F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Combustible solids, category 3
Combustible liquids, category 3
Self-heating substances and mixtures, categories 1, 2
Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
Organic peroxides, types B, C, D, E, F

GHS05
Corrosive

Corrosive to metals, category 1

GHS03
Harmful

Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, categories 2, 3
Eye irritation, category 2A
Skin sensitization, category 1
Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects

Not used

with the "skull and crossbones" pictogram
for skin or eye irritation if:
the "corrosion" pictogram also appears
the "health hazard" pictogram is used to indicate respiratory sensitization

GHS08
Health hazard

Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A, 1B, 2
Carcinogenicity, categories 1A, 1B, 2
Reproductive toxicity, categories 1A, 1B, 2
Specific target organ toxicity following single exposure, categories 1, 2
Specific target organ toxicity following repeated exposure, categories 1, 2
Aspiration hazard, categories 1, 2

GHS09
Environmental hazard

Acute hazards to the aquatic environment, category 1
Chronic hazards to the aquatic environment, categories 1, 2
Environmental toxicity, categories 1, 2

Safety & Transport Information

Risk Codes:

R11 - Highly flammable
R14/15 - Reacts violently with water, liberating extremely flammable gases
R15 - Contact with water liberates extremely flammable gases
R17 - Spontaneously flammable in air
R34 - Causes burns
R38 - Irritating to skin
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R65 - Harmful: may cause lung damage if swallowed
R66 - Repeated exposure may cause skin dryness or cracking
R67 - Vapours may cause drowsiness and dizziness

Safety Codes:

S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S33 - Take precautionary measures against static discharges
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S9 - Keep container in a well-ventilated place

Hazard Classes:

4.3

Hazard Symbols:

F, C, N

Storage temperature :

2-8°C

RID/ADR certification :

UN 3394 4.2 / PG 1

Alternative Distributors of [tert-Butyllithium, nominally 1.5M in n-pentane]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Downloads

Mol File:

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MSDS:

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tert-Butyllithium, nominally 1.5M in n-pentane, packaged under Argon in resealable ChemSeal bottles