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Tert-butyldimethylsilyl chloride ( TBMS )

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Formula: (CH3)3CSi(CH3)2Cl
CAS: 18162-48-6

Identification

Structural Formula
Tert-butyldimethylsilyl chloride ( TBMS )
CAS:
18162-48-6
EINECS:
242-042-4
Molecular Formula:
(CH3)3CSi(CH3)2Cl
MDL:
MFCD00000501
Synonym:
silane tbm2 ; tbume2si-cl ; tbdmschloride ; cb2790 ; tbscl ; tbdmscl ; tbdmcl ; bdcs ; tbdmsci ; tbdmcs




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Prices & Availability




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Properties for Tert-butyldimethylsilyl chloride ( TBMS )

Molecular Weight:
150.72 g·mol−1
Density:
0.87 g/mL at 20 °C(lit.)
Melting point:
86-89 °C
Boiling point:
125 °C(lit.)
Flash point:
73 ºF
Solubility:
Chloroform
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2

Safety & Transport Information

Risk Codes:
R10 - Flammable
R11 - Highly flammable
R19 - May form explosive peroxides
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed
R22 - Harmful if swallowed
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed
R34 - Causes burns
R35 - Causes severe burns
R36/37/38 - Irritating to eyes, respiratory system and skin
R37 - Irritating to respiratory system
R40 - Limited evidence of a carcinogenic effect
R45 - May cause cancer
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R63 - Possible risk of harm to the unborn child
R65 - Harmful: may cause lung damage if swallowed
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S25 - Avoid contact with eyes
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27 - Take off immediately all contaminated clothing
S28 - After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
S29 - Do not empty into drains
S33 - Take precautionary measures against static discharges
S36/37 - Wear suitable protective clothing and gloves
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S46 - If swallowed, seek medical advice immediately and show this container or label
S53 - Avoid exposure - obtain special instructions before use
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
Hazard Classes:
4.1
Hazard Symbols:
C, F, T, Xn
Hazard symbol T Hazard symbol C Hazard symbol F Hazard symbol Xn
Storage temperature :
Store at 5 °C
RID/ADR certification :
UN 2925 4.1 / PG 2
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Alternative Distributors of [Tert-butyldimethylsilyl chloride ( TBMS )]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Spectrum Chemical Mfg. Corp. | Hangzhou Think Chemical Co., Ltd. | Chem-Impex International, Inc. | HuaiBei SanHe Developing Co., Ltd. | Hisyntech Corporation Limited | Unibest Industrial Co., Ltd. | Kingfirst Chemical (Nanjing) Co., Ltd. | Xiang Ding Chemical International Co., Ltd | Pharmasi Chemicals Co., Ltd. | Taizhou Taifeng Chemical Co., Ltd. | Wintersun Chemical | Honour Enterprise Limited | Henan Yuchen Fine Chemical Co., Ltd. | Shanghai AOKChem Group Limited | Shanghai Chemsors chemicals Co., Ltd. | Ruiyuan Group Limited | Jinzhou Donghui PharmaChem Co., Ltd. | Baisun Hongkong Import and Export Co., Ltd. | Ruiyi Medical Co., Ltd. | Wuxi Mizat Chemical Technology Co., Ltd. | Shanghai Hanhong Chemical Co., Ltd. | Shijiazhuang JuSha Imp.& Exp. Co.Ltd | Win-Win Chemical Co., Limited | Jinan Great Chemical Co., Ltd. | Shanghai Egoalchem Co., Ltd. | Nantong Qihai Chemicals Co., Ltd. | ZhangJiaGang CAE International Trading Co., Ltd. | Ningbo Hi-Tech Biochemicals Co., Ltd. | Rif Life Science Co., Limited | Suzhou Sibian Chemical Technology Co., Ltd. | East Chemical Industry Co., Ltd. | Zhejiang Kaili Industrial Co., Ltd. | Yongyi Chemicals Group Co., Ltd. | Beijing Yangguang Furuide Chemical Co., Ltd. | Watson International Ltd | Aopharm | BOC Sciences | Suzhou Bichal Biological Technology Co., Ltd. | Jinan Haohua Industry Co., Ltd. | Suzhou Vosun Chemical Co.,Ltd. | Trademax Phamaceuticals & Chemicals Co., Ltd. | Sino Rarechem Labs Co. Ltd. | Changzhou Union Chemicals Co.,Ltd. | Wanko Chemical Co., Ltd.

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