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Tebbe reagent

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Formula: C13H18AlClTi 10*
CAS: 67719-69-1
search Element: reagent tebbe

Identification

Structural Formula
Tebbe reagent
CAS:
67719-69-1
EINECS:
Molecular Formula:
C13H18AlClTi 10*
MDL:
MFCD00151575
Synonym:
tebbe reagent solution ; tebbe's reagent ; tebbe reagent, 0.5m solution in toluene, spcseal ; tebbe reagent ; ca.0.5mol/ltoluenesolution ; tebbe reagent, 0.5m solution in toluene ; tebbe reagent, 0.5m solution in toluene, acroseal ; tebbe ; tebbe reagent (ca. 0.5mol/l in toluene) ; titanium,í-chlorobis(è5-2,4-cyclopentadien-1- yl)(dimethylaluminum)-í-methylene- ; tebbe reagent solution, ~0.5 m in toluen e




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Tebbe Reagent solution
Hangzhou Cherry Pharmaceutical Technology Co., Ltd.
HCPT336616830
Tebbe Reagent (ca. 0.5mol/L in Toluene)
TCI Chemicals (India) Pvt. Ltd.
C1411
mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
Alfa (A Johnson Matthey Company)
A1612848384

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Properties for Tebbe reagent

Molecular Weight:
284.58 g·mol−1
Density:
0.96 g/mL at 20 °C
Flash point:
34 ºF
Physical Description:
dark red to purple solution
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R34 - Causes burns
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R63 - Possible risk of harm to the unborn child
R65 - Harmful: may cause lung damage if swallowed
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
Hazard Classes:
4.3
Hazard Symbols:
F, C
Hazard symbol C Hazard symbol F
Storage temperature :
Refrigerator
RID/ADR certification :
UN 2924 3 / PG 2
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Alternative Distributors of [Tebbe reagent]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Jinan Haohua Industry Co., Ltd.

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Downloads

Mol File:
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MSDS:
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