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TBTU

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Formula: C11H16N5O.BF4
CAS: 125700-67-6
search Element: tbtu

Identification

Structural Formula
TBTU
CAS:
125700-67-6
EINECS:
Molecular Formula:
C11H16N5O.BF4
MDL:
MFCD00077413
SMILES:
[B-](F)(F)(F)F.CN(C)C(=[N+](C)C)ON1C2=CC=CC=C2N=N1
Synonym:
tbtu extrapure ; benzotriazolyl tetramethyluronium fluoroborate ; knorr reagent ; tbtu (knorr reagent) ; 1h-benzotriazolium-1-[bis(dimethylamine) ; o-benzotriazol-1-yl-n,n,n',n'-tetra- & ; tetrafluoroborate tbtu ; o-(benzotriazol-1-yl)-n,n,n',n'-tetramethyluro ; tbpipu ; tbtu


Description

TBTU is a coupling reagent used for solid-phase peptide synthesis. The compound has been used to study ten different phosphonium and uronium salt-based coupling reagents, which are used to synthesize four peptides. TBTU has been documented as a coupling reagent to synthesize a tetrahydrocarbazole substituted dipeptide in a multi-gram solid-phase synthesis. The compound has also been incorporated with HOBt (hydroxybenzotriazole dihydrate) as a carboxyl activator before the coupling of a C-terminal amino acid with a success rate of 100% coupling.


Suppliers

XD BIOCHEMS Ltd
XB60180
Shandong Ench Chemical Co.,Ltd
SECC120600
Kingreat Chemistry Company Limited
KCCL136680
Changzhou Union Chemicals Co.,Ltd.
CUCC136680
Advanced Chemtech, Inc. USA
ACU108432
Xiamen Equation Chemical Co.,Ltd
XECC128640
Sancai Industry Co.,Ltd.
SIC96384
Daming Changda Co., Ltd.
LLB00742
Reafon Industry Co., Ltd.
RI100300
Reafon Industry Co., Ltd.
RF-C133
GL Biochem (Shanghai) Ltd.
00705
Aecochem Corp.
AC56168
Hangzhou Keying Chem Co., Ltd.
HKC120480
AK Scientific, Inc.
AS76228
Simagchem Corporation
SC84252
Capot Chemical Co., Ltd.
12754
Santa Cruz Biotechnology, Inc.
202831
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Prices & Availability




Data is processed


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Properties for TBTU

Molecular Weight:
321.08 g·mol−1
Melting point:
205 °C (dec.)(lit.)
Solubility:
acetonitrile: 0.1 g/mL, clear
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R2 - Risk of explosion by shock, friction, fire or other sources of ignition
R36/37/38 - Irritating to eyes, respiratory system and skin
R5 - Heating may cause an explosion
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S35 - This material and its container must be disposed of in a safe way
S36 - Wear suitable protective clothing
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S37/39 - Wear suitable gloves and eye/face protection
Hazard Symbols:
Xi, F, E
Hazard symbol E Hazard symbol F Hazard symbol Xi
Storage temperature :
2-8°C
x

Alternative Distributors of [TBTU]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Huasheng Chemical Co., Limited | Shanghai International Pharmaceutical Co., Ltd. | Suzhou Tianma Specialty Chemicals Co., Ltd. | Shanghai Eagle Chemical Co., Ltd. | AGTC Bioproducts Ltd. | AA Biochem Inc. | Pharmasi Chemicals Co., Ltd. | Ruiyuan Group Limited | Chemrio International Limited | Share Chemical Co., Ltd. | Suzhou Rovathin Pharmatech Co., Ltd | Shanghai Hanhong Chemical Co., Ltd. | Shijiazhuang JuSha Imp.& Exp. Co.Ltd | Nantong Qihai Chemicals Co., Ltd. | Rif Life Science Co., Limited | Nantong Huiding International Co., Ltd | Hangzhou Ocean Chemical Co., Ltd. | Jinan Haohua Industry Co., Ltd. | Suzhou Vosun Chemical Co.,Ltd. | Xiamen Hisunny Chemical Co., Ltd. | Changzhou Union Chemicals Co.,Ltd.

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