(2S,4S)-1-tBoc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine | CAS 61478-28-2

Element: diphenylphosphinomethyl diphenylphosphino pyrrolidine tboc

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C-S » Chemicals » tboc-diphenylphosphino-diphenylphosphinomethyl-pyrrolidine-PX34430

Identification

(2S,4S)-1-tBoc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine

CAS:

61478-28-2

EINECS:

Molecular Formula:

C₃₄H₃₇NO₂P₂

MDL:

MFCD01631275

SMILES:

CC(C)(C)OC(=O)N1C[C@H](C[C@H]1CP(C1=CC=CC=C1)C1=CC=CC=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Synonym:

(2s,4s)-(-)-1-tboc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine ; (2s,4s)-(-)-n-boc-4-diphenylphosphino-2-diphenylphosphinomethyl-pyrrolidine ; boc-diphenylphosphino-diphenylphosphino- methyl-pyrrolidine ; (2s,4s)-1-boc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine ; bppm, (2s,4s)-1-boc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine ; (2s,4s)-n-butoxycarbonyl-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolid ; (2s,4s)-bppm ; (-)-bppm ; bppm ; (2s,4s)-(-)-1-boc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine

Description

Chiral phosphine ligand for the rhodium catalyzed asymmetric hydrogenation of ketones and olefins. α-Amino acids are obtained in very high optical purity Hydrogenation of ketones to alcohols Hydroformylation.

Suppliers

Santa Cruz Biotechnology, Inc.

256383

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Prices & Availability

Data is processed

Properties for (2S,4S)-1-tBoc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine

Molecular Weight:

553.61 g·mol−1

Melting point:

96-100 °C

Hazard Statements

GHS03
Harmful

Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, categories 2, 3
Eye irritation, category 2A
Skin sensitization, category 1
Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects

Not used

with the "skull and crossbones" pictogram
for skin or eye irritation if:
the "corrosion" pictogram also appears
the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:

R36/37/38 - Irritating to eyes, respiratory system and skin

Safety Codes:

S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36 - Wear suitable protective clothing

Hazard Symbols:

Storage temperature :

2-8°C

Alternative Distributors of [(2S,4S)-1-tBoc-4-diphenylphosphino-2-(diphenylphosphinomethyl)pyrrolidine]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

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MSDS:

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