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N-Phenyl-bis(trifluoromethanesulfonimide)

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Formula: C8H5F6NO4S2
CAS: 37595-74-7
search Element: trifluoromethanesulfonimide phenyl
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Identification

Structural Formula
N-Phenyl-bis(trifluoromethanesulfonimide)
CAS:
37595-74-7
EINECS:
Molecular Formula:
C8H5F6NO4S2
MDL:
MFCD00000404
SMILES:
FC(F)(F)S(=O)(=O)N(C1=CC=CC=C1)S(=O)(=O)C(F)(F)F
Synonym:
n,n-bis(trifluoromethylsulfonyl)aniline ; phenyl triflimide ; n-phenyltrifluoromethanesulfonimide ; phenyltrifluoromethanesulfonimide ; nsc 240874 ; n,n-bis(trifluoromethylsufonyl)aniline ; n-phenyltrifluoromethanesulphonimide ; n-phenyl-bis-(trifluormethansulfonimid) ; n-phenyl bis trifluorosulphonamide ; n-bis(trifluoromethylsulfonyl)aniline


Description

Mild triflating reagent. Employed recently to convert a ketone to an enol triflate with KHMDS and thence an olefin with Pd(PPh3)4 and Bu3SnH.


Suppliers

DSL Chemicals (Shanghai) Co., Ltd.
C019752
Santa Cruz Biotechnology, Inc.
253122
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Prices & Availability




Data is processed


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Properties for N-Phenyl-bis(trifluoromethanesulfonimide)

Molecular Weight:
357.25 g·mol−1
Melting point:
100-102 °C(lit.)
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36 - Wear suitable protective clothing
Hazard Classes:
irritant
Hazard Symbols:
Xi
Hazard symbol Xi
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Alternative Distributors of [N-Phenyl-bis(trifluoromethanesulfonimide)]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Lanzhou Boc chem Co., Ltd. | BOC Sciences | Alfa Aesar, a Johnson Matthey Company | ABCR GmbH & Co. KG | Gihi Chemicals Co., Limited | TCI Europe NV | Shanghai ChemVia Co., Ltd | scienTEST | ChengDu KaiXin Technology Development Co., Ltd. | Bepharm Ltd. | Shanghai Sinofluoro Scientific Co., Ltd. | Suzhou Vosun Chemical Co.,Ltd. | AOKBIO Co., Ltd. | Shanghai Arbor Chemical Co., Ltd. | 3Way Pharm Inc. | Zhejiang Kaili Industrial Co., Ltd. | Sino Rarechem Labs Co. Ltd.

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