Palladium hydroxide on carbon | CAS 12135-22-7

Element: hydroxide palladium carbon

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C-S » Chemicals » palladium-hydroxide-carbon-PX52561

Identification

Palladium hydroxide on carbon

CAS:

12135-22-7

EINECS:

235-219-2

Molecular Formula:

H₂O₂Pd

MDL:

MFCD00064599

SMILES:

[OH-].[OH-].[Pd+2]

Synonym:

pd(oh)2 ; pd(oh)2/c ; escat 1621 ; pearlman's catalyst ; escat 1471 ; escat 1431 ; escat 1421 ; palladium(ii) hydroxide ; escat 1931 ; palladium(2+) dihydroxide ; escat 1921 ; palladiumdihydroxide ; escat 1951 ; escattm 11

Description

Palladium hydroxide on carbon catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes. The addition of Pd/C to Pd(OH)₂/C improves the efficiency of N- or O-debenzylation. Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proved successful where other palladium-on-carbon catalysts have failed.

Suppliers

Xiamen Equation Chemical Co.,Ltd

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Carbone Scientific Co., Ltd.

CS32489744

Simagchem Corporation

SC24367308

Santa Cruz Biotechnology, Inc.

250642

Dayang Chem (Hangzhou) Co.,Ltd.

DC359614384

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Prices & Availability

Data is processed

Properties for Palladium hydroxide on carbon

Molecular Weight:

140.4347 g·mol−1

Boiling point:

100 °C at 760 mmHg

Solubility:

Insoluble in water

Physical Description:

black powder

Safety & Transport Information

Risk Codes:

R11 - Highly flammable
R36/37/38 - Irritating to eyes, respiratory system and skin

Safety Codes:

S14 - Keep away from ... (incompatible materials to be indicated by the manufacturer)
S16 - Keep away from sources of ignition - No smoking
S20/21 - When using do not eat, drink or smoke
S22 - Do not breathe dust
S24/25 - Avoid contact with skin and eyes
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27 - Take off immediately all contaminated clothing
S33 - Take precautionary measures against static discharges
S36 - Wear suitable protective clothing
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S7/9 - Keep container tightly closed and in a well-ventilated place

Hazard Classes:

4.1

Hazard Symbols:

F, Xi

RID/ADR certification :

UN1325

Alternative Distributors of [Palladium hydroxide on carbon]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

TCI Europe NV | Ruiyuan Group Limited | Chempion International Co Ltd | Hangzhou Ocean Chemical Co., Ltd. | scienTEST

Downloads

Mol File:

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MSDS:

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