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Hazard Statements
GHS02
Flammable
- Flammable gases, category 1
- Flammable aerosols, categories 1, 2
- Flammable liquids, categories 1, 2, 3
- Flammable solids, categories 1, 2
- Self-reactive substances and mixtures, types B, C, D, E, F
- Pyrophoric liquids, category 1
- Pyrophoric solids, category 1
- Combustible solids, category 3
- Combustible liquids, category 3
- Self-heating substances and mixtures, categories 1, 2
- Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
- Organic peroxides, types B, C, D, E, F
GHS05
Corrosive
- Corrosive to metals, category 1
GHS03
Harmful
- Acute toxicity (oral, dermal, inhalation), category 4
- Skin irritation, categories 2, 3
- Eye irritation, category 2A
- Skin sensitization, category 1
- Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects
Not used
- with the "skull and crossbones" pictogram
- for skin or eye irritation if:
- the "corrosion" pictogram also appears
- the "health hazard" pictogram is used to indicate respiratory sensitization
Safety & Transport Information
Toxic. Explosive reaction with thiophosphoryl chloride or vanadium trichloride. A Grignard reagent. When heated to decomposition it emits toxic fumes of I−. See also IODIDES and MAGNESIUM COMPOUNDS.
Risk Codes:
R11 - Highly flammable
R12 - Extremely flammable
R14/15 - Reacts violently with water, liberating extremely flammable gases
R19 - May form explosive peroxides
R22 - Harmful if swallowed
R34 - Causes burns
R66 - Repeated exposure may cause skin dryness or cracking
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S7/8 - Keep container tightly closed and dry
RID/ADR certification :
UN 3399 4.3 / PG 1
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Alternative Distributors of [Methylmagnesium iodide; 33% in Ethyl ether]
Producers or manufacturers change the product range from time to time.
The following companies
have appeared as suppliers in the past / currently not verified
TCI Europe NV | Pfaltz & Bauer, Inc.