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Manganese,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-

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Formula: C36H52ClMnN2O2
CAS: 135620-04-1
search Element: cyclohexanediylbis dimethylethyl methylidyne manganese phenolato nitrilo chloro
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Identification

Structural Formula
Manganese,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-
CAS:
135620-04-1
EINECS:
Molecular Formula:
C36H52ClMnN2O2
MDL:
MFCD02101663
Synonym:
(s,s)(+)n,n'-bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco ; (s,s)-jacobsen's catalyst ; (s,s)-n,n'-bis(3,5-di-tert-butylsalicyl- idene)-1,2-cyclohexanediamino-mn-cl ; (s,s)-jacobsen catalyst ; (s,s)-jacobsen's catalyst manganese(iii) chloride complex ; jacobsen's catalyst ; (s,s)-jacobsencat. ; (s,s)-jacbosen ; (+)-bis(3,5-di-t-bu-salicyl.)-1,2-cyclo- hexanediamino-mn cl ; (s,s)-(+)n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(iii) chlo




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Manganese,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-(SP-5-13)-
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Properties for Manganese,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-

Molecular Weight:
635.2 g·mol−1
Melting point:
330-332 °C(lit.)
Physical Description:
dark brown powder
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36 - Wear suitable protective clothing
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
Hazard Symbols:
Xi
Hazard symbol Xi
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Alternative Distributors of [Manganese,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG

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