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(Iodomethyl)trimethylsilane

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Formula: (CH3)3SiCH2I
CAS: 4206-67-1
search Element: trimethylsilane iodomethyl
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Identification

Structural Formula
(Iodomethyl)trimethylsilane
CAS:
4206-67-1
EINECS:
224-123-6
Molecular Formula:
(CH3)3SiCH2I
MDL:
MFCD00001077
SMILES:
IC[Si](C)(C)C
Synonym:
(iodomethyl)trimethylsilane ; (trimethylsilyl)iodomethane ; (iodomethyl)trimethylsilane >=99.0% (gc) ; silane, (iodomethyl)trimethyl- ; (trimethylsilyl)methyl iodide ; (iodomethyl)trimethylsilane,99% ; (iodomethyl)trimethylsilane, 99% 5ml ; (iodomethyl)trimethylsilane 99% ; trimethyl(iodomethyl)silane


Description

Starting material in preparing 2-(trimethylsilyl)ethyl-triphenylphosphonium iodide used for the synthesis of allyl silanes. Employed for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions.


Suppliers

Ambeed, Inc.
A493482
+
Shanghai Worldyang Chemical Co., Ltd.
SWC19987992
+
Leap Chem Co., Ltd
LC9722916
+
Santa Cruz Biotechnology, Inc.
252908
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CAS equal suppliers

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Xiamen Equation Chemical Co.,Ltd
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Junwee Chemical Co., Ltd.
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BLD Pharmatech Ltd
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Chemlyte Solutions
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Prices & Availability




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Properties for (Iodomethyl)trimethylsilane

Molecular Weight:
214.12 g·mol−1
Density:
1.443 g/mL at 25 °C(lit.)
Boiling point:
139-141 °C(lit.)
Flash point:
89 ºF
Physical Description:
clear yellow to brown liquid
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R10 - Flammable
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S24/25 - Avoid contact with skin and eyes
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36 - Wear suitable protective clothing
Hazard Classes:
3.2
Hazard Symbols:
Xi
Hazard symbol Xi
Storage temperature :
Flammables area
RID/ADR certification :
UN 2924 3 / PG 3
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Alternative Distributors of [(Iodomethyl)trimethylsilane]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

BOC Sciences | ABCR GmbH & Co. KG | Jinan Great Chemical Co., Ltd. | Gelest, Inc. | TCI Europe NV | Pharmasi Chemicals Co., Ltd. | Chengdu Qiaofeng Technological Development Co., Ltd. | Balmxy Pharmaceutical Co., Ltd | East Chemical Industry Co., Ltd.

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