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Hazard Statements
GHS05
Corrosive
- Corrosive to metals, category 1
GHS03
Harmful
- Acute toxicity (oral, dermal, inhalation), category 4
- Skin irritation, categories 2, 3
- Eye irritation, category 2A
- Skin sensitization, category 1
- Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects
Not used
- with the "skull and crossbones" pictogram
- for skin or eye irritation if:
- the "corrosion" pictogram also appears
- the "health hazard" pictogram is used to indicate respiratory sensitization
Safety & Transport Information
Poison by intravenous route. Mildly toxic by inhalation. A skin, severe eye, and mucous membrane irritant. Will react violently with water or steam to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of Cl−. See also GERMANIUM COMPOUNDS.
Risk Codes:
R14 - Reacts violently with water
R34 - Causes burns
R37 - Irritating to respiratory system
R40 - Limited evidence of a carcinogenic effect
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S25 - Avoid contact with eyes
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27 - Take off immediately all contaminated clothing
S36 - Wear suitable protective clothing
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S8 - Keep container dry
Hazard Symbols:
C
RID/ADR certification :
UN 3390 6.1 / PG 1
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Alternative Distributors of [Germanium tetrachloride]
Producers or manufacturers change the product range from time to time.
The following companies
have appeared as suppliers in the past / currently not verified
Inter-Chemical Ltd. | Air Products Chemicals Europe B.V. | Air Products and Chemicals, Inc. | Gelest, Inc. | ABCR GmbH & Co. KG | BOC Sciences | Jinan Haohua Industry Co., Ltd. | Skyrun Industrial Co., Ltd. | Pfaltz & Bauer, Inc. | Gihi Chemicals Co., Limited | Hangzhou Dayangchem Co. Ltd.