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(-)-DIP-Chloride™

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Formula: C20H34BCl
CAS: 85116-37-6
search Element: chloride trade
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Identification

Structural Formula
(-)-DIP-Chloride™
CAS:
85116-37-6
EINECS:
Molecular Formula:
C20H34BCl
MDL:
MFCD00074807
SMILES:
B([C@@H]1CC2CCC([C@H]1C)C2(C)C)([C@@H]3CC4CCC([C@H]3C)C4(C)C)Cl
Synonym:
()-dip-chloride solution ; (-)-diisopinocampheyl chloroborane ; (-)-dip-chloride tm solution ; (-)-dip-chloride (~60% in heptane) ; (-)-b-chlorodiisopinocampheylborane ; (-)-dip-chloride ; (-)-diisopincampheyl chloroborane ; (-)-ipc2bcl ; (-)-dip-chloride(tm)


Description

Reagent employed in an enantioselective reduction of (chloroacetyl) benzofurans to chlorohydrins which serve as intermediates for the corresponding epoxides and aminoalcohols. Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones(1) and for preparing ∫-amino alcohols.


Suppliers

Santa Cruz Biotechnology, Inc.
252746
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Prices & Availability




Data is processed


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Properties for (-)-DIP-Chloride™

Molecular Weight:
320.75 g·mol−1
Density:
0.954 g/mL at 25 °C
Melting point:
52-56 °C(lit.)
Boiling point:
66-69 °C
Flash point:
82 ºF
Physical Description:
solutio
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2
GHS09

GHS09
Environmental hazard
  • Acute hazards to the aquatic environment, category 1
  • Chronic hazards to the aquatic environment, categories 1, 2
  • Environmental toxicity, categories 1, 2

Safety & Transport Information

Risk Codes:
R10 - Flammable
R11 - Highly flammable
R12 - Extremely flammable
R20/22 - Harmful by inhalation and if swallowed
R34 - Causes burns
R37 - Irritating to respiratory system
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 - Possible risk of impaired fertility
R65 - Harmful: may cause lung damage if swallowed
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S29 - Do not empty into drains
S33 - Take precautionary measures against static discharges
S36/37 - Wear suitable protective clothing and gloves
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S9 - Keep container in a well-ventilated place
Hazard Symbols:
C, F+, N, F
Hazard symbol C Hazard symbol N Hazard symbol F+ Hazard symbol F
Storage temperature :
2-8°C
RID/ADR certification :
UN 3261 8 / PG 2
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Alternative Distributors of [(-)-DIP-Chloride™]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Molekula GmbH | Nantong Qihai Chemicals Co., Ltd. | BOC Sciences | Changzhou Weijia Chemical Co.,Ltd. -WJCHEM- | Clearsynth Canada INC.

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