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2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl

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Formula: C33H49P
CAS: 564483-18-7
search Element: dicyclohexylphosphino triisopropylbiphenyl
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Identification

Structural Formula
2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl
CAS:
564483-18-7
EINECS:
Molecular Formula:
C33H49P
MDL:
MFCD04117682
SMILES:
CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4)C(C)C
Synonym:
xphos, >=98% ; x-phos, chemdose(r) tablets ; 98% xphos ; 2-(dicyclohexylphosphino)-2',4 ; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1, ; xphos 97% ; 5-bromo-4-chloro-3-indolyl phosphate ; x-phos ; 2-dicyclohexylphosphino-2 ; x-phos, chemdose? tablets


Description

2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl is a ligand for increased scope of Pd-catalyzed amination and amidation via arene sulfonates, aryl halides. It is a ligand used in a Pd-catalyzed Suzuki coupling leading to C-15 analogs of vindoline and direct annulation of 2-haloanilines to indoles and tryptophans.


Suppliers

Santa Cruz Biotechnology, Inc.
251742
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Properties for 2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl

Molecular Weight:
476.72 g·mol−1
Melting point:
187-190 °C(lit.)
Boiling point:
~569.8° C at 760 mmHg (Predicted)
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Hazard Statements

GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2

Safety & Transport Information

Risk Codes:
R22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin
R40 - Limited evidence of a carcinogenic effect
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37 - Wear suitable protective clothing and gloves
S37/39 - Wear suitable gloves and eye/face protection
Hazard Symbols:
Xn
Hazard symbol Xn
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Alternative Distributors of [2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Watson International Ltd | Mengjiangnan Chemical Co., Ltd | Intatrade Chemicals GmbH | AK Scientific, Inc. | Changzhou Weijia Chemical Co.,Ltd. -WJCHEM- | Suzhou Vosun Chemical Co.,Ltd. | Sino Rarechem Labs Co. Ltd. | All Right Chemical Co., Ltd.

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