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2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl

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Formula: C26H36NP
CAS: 213697-53-1

Identification

Structural Formula
2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl
CAS:
213697-53-1
EINECS:
Molecular Formula:
C26H36NP
MDL:
MFCD02183572
SMILES:
CN(C)C1=CC=CC=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4
Synonym:
davephos (2-(di-tert-butylphosphino)biphenyl) ; 2-dicyclohexylphosphino-2'-(n, ; 2-dicyclohexylphosphino-2'-(n,n-dimethy& ; davephos ; 2-dicyclohexylphosphino-2'-(n,n-dimethylamino)- ; davep ; davephos 97% ; 2-dicyclohexylphosphino-2-(n,n-dimethylamino)biph ; 98% davephos ; 2-dimethylamino-2'-dicyclohexylphosphinobiphenyl


Description

Useful ligand for Pd-catalyzed C-N bond formation; amination of aryl halides containing hydroxyl, amide, or enolizable ketones. Ligand used in a Pd-catalyzed Suzuki aryl-aryl coupling leading to benzodioxepines.


Suppliers

BLD Pharmatech Ltd
BP486014580
Chemlyte Solutions
CS486014580
FUDI Chemical Co. Ltd.
FCC594023760
Autech Industry Co.,Limited
AIC729029160
Junwee Chemical Co., Ltd.
JC675020250
Xiamen Equation Chemical Co.,Ltd
XECC864043200
Finetech Industry Limited
FIL675027000
Xiamen Hisunny Chemical Co., Ltd.
XHC891035640
Simagchem Corporation
SC567017010
Amadis Chemical Company Limited
ACCL837041850
Santa Cruz Biotechnology, Inc.
251741
Dayang Chem (Hangzhou) Co.,Ltd.
DC837033480
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Haihang Industry Co., Ltd.
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Angene International Limited
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Prices & Availability




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Properties for 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl

Molecular Weight:
393.54 g·mol−1
Melting point:
121-124 °C(lit.)
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
Hazard Classes:
air sensitive
Hazard Symbols:
Xi, Xn
Hazard symbol Xn Hazard symbol Xi
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Alternative Distributors of [2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Finetech Industry Limited | ABCR GmbH & Co. KG | ShangHai Top Descendants Bioscience Co., Ltd | Jinan Great Chemical Co., Ltd. | Gihi Chemicals Co., Limited | Anix-Chem Limited | Rongkang Industry Co.,Ltd - (NSTU Chemicals Hanggzhou Co.,) | Watson International Ltd | Mengjiangnan Chemical Co., Ltd | TCI Europe NV | Merseburger Spezialchemikalien | Pharmasi Chemicals Co., Ltd. | Ark Pharm, Inc. | Ningbo Inno Pharmchem Co. Ltd. | Matrix Scientific | Changzhou Weijia Chemical Co.,Ltd. -WJCHEM- | Suzhou Rovathin Pharmatech Co., Ltd | Bepharm Ltd. | Win-Win Chemical Co., Limited | Shanghai AOKChem Group Limited | Suzhou Vosun Chemical Co.,Ltd. | ShangHai Biochempartner Co., Ltd. | TCASChem Tech Co., Ltd. | Suzhou Sibian Chemical Technology Co., Ltd. | Shanghai Raise Chemical Technology Co., Ltd. | East Chemical Industry Co., Ltd. | Zhejiang Kaili Industrial Co., Ltd. | Sino Rarechem Labs Co. Ltd. | Beijing Yangguang Furuide Chemical Co., Ltd. | All Right Chemical Co., Ltd.

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