(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer | CAS 12148-71-9

Element: cyclooctadiene iridium methoxy dimer

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C-S » Chemicals » cyclooctadiene-methoxy-iridium-dimer-PX54689

Identification

(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer

CAS:

12148-71-9

EINECS:

Molecular Formula:

C₁₈H₃₀ Ir₂ O₂

MDL:

MFCD08459360

SMILES:

C[OH2+].C[OH2+].C1/C=CCC/C=CC1.C1/C=CCC/C=CC1.[Ir].[Ir]

Synonym:

bis(1,5-cyclooctadiene) di-u-methoxydiiridium ; bis(1,5-cyclooctadiene)dimethoxydiiridium ; [ir(ome)(1,5-cod)]2 ; bis(h4-1,5-cyclooctadiene)-di-m-methoxodiiridium ; bis((1,5-cyclooctadiene)(m-methanolato)iridium) ; -methoxy)iridium(i) dimer ; di-m-methoxobis(1,5-cyclooctadiene)diiridium ; iridium,dimethoxybis(1,5-cyclooctadiene)di- (7ci) ; 1,5 cyclooctadiene(μ ; [ir(ome)(1 ; bis(1,5-cyclooctadiene) di-mu-methoxydii ; bis[(1,5-cyclooctadiene)(methanolato)iridium] ; bis(cyclooctadiene(methoxy)iridium) ; iridium, bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-m-methoxydi- ; 1,5-cyclooctadiene, iridium complex ; bis(1,5-cyclooctadiene)-di-m-methoxodiiridium ; methoxy(cyclooctadiene)iridium(i) dimer ; 5-cod)]2

Description

a catalyst for preparation of heteroaryl fused indole ring systems, borylation/suzuki-miyaura coupling, metalation-suzuki cross-coupling procedure for synthesis of heterobiaryls and biaryls. Also used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation. Perhaps the most useful application is highly regio- and enantioselection asymmetric hydroboration.

Suppliers

Quzhou Rundong Chemical Co., Ltd.

QRC742529700

Carbone Scientific Co., Ltd.

CS630018900

AK Scientific, Inc.

AS427512825

Simagchem Corporation

SC472514175

Amadis Chemical Company Limited

ACCL697534875

Santa Cruz Biotechnology, Inc.

229832

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Prices & Availability

Data is processed

Properties for (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer

Molecular Weight:

662.86 g·mol−1

Melting point:

154-177 °C

Physical Description:

yellow solid

Hazard Statements

GHS03
Harmful

Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, categories 2, 3
Eye irritation, category 2A
Skin sensitization, category 1
Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects

Not used