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Copper(I) trifluoromethanesulfonate benzene complex

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Formula: C8H6Cu2F6O6S2
CAS: 42152-46-5
search Element: trifluoromethanesulfonate benzene complex copper
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Identification

Structural Formula
Copper(I) trifluoromethanesulfonate benzene complex
CAS:
42152-46-5
EINECS:
255-686-6
Molecular Formula:
C8H6Cu2F6O6S2
MDL:
MFCD00043300
SMILES:
C1=CC=CC=C1.C(F)(F)(F)S(=O)(=O)O.C(F)(F)(F)S(=O)(=O)O.[Cu].[Cu]
Synonym:
trifluoromethanesulfonic acid, copper(i) salt ; bis[copper (i) trifluoromethanesulfonate], benzene complex ; copper(i) triflate benzene complex ; trifluoromethanesulfonic acid copper(i) salt benzene complex ; copper(i) trifluoromethanesulfonate benzene complex ; copper(i) trifluoromethanesulfonate benzene complex ,88% ; cuprous trifluoromethanesulfonate benzene complex ; copper(i) trifluoromethanesulfonate benzene complex,90% ; trifluoromethanesulfonicacidcopper(1)saltbenzenecomplex ; copper (i) trifluoromethanesulfonate benzene complex 90%


Description

Copper(I) trifluoromethanesulfonate benzene complex has catalyzed allylic oxidation of cyclic alkenes enantioselectively. In combination with amino acid-based chiral phosphine ligands, catalyzes asymmetric conjugate additions of alkylzincs to acyclic å,∫-unsaturated ketones, affording ∫-alkylcarbonyls in high yield and with excellent enantioselectivity.


Suppliers

BLD Pharmatech Ltd
BP459013770
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Santa Cruz Biotechnology, Inc.
252629
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Properties for Copper(I) trifluoromethanesulfonate benzene complex

Molecular Weight:
503.34 g·mol−1
Melting point:
160 °C (dec.)(lit.)
Flash point:
45 ºF
Physical Description:
grey-greenish powder
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
    • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36 - Wear suitable protective clothing
Hazard Classes:
4.1
Hazard Symbols:
F
Hazard symbol F
Storage temperature :
Refrigerator
RID/ADR certification :
UN 3175 4.1 / PG 2
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Alternative Distributors of [Copper(I) trifluoromethanesulfonate benzene complex]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG | TCI Europe NV | BOC Sciences | Primex EHF

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MSDS:
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