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Hazard Statements
GHS02
Flammable
- Flammable gases, category 1
- Flammable aerosols, categories 1, 2
- Flammable liquids, categories 1, 2, 3
- Flammable solids, categories 1, 2
- Self-reactive substances and mixtures, types B, C, D, E, F
- Pyrophoric liquids, category 1
- Pyrophoric solids, category 1
- Combustible solids, category 3
- Combustible liquids, category 3
- Self-heating substances and mixtures, categories 1, 2
- Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
- Organic peroxides, types B, C, D, E, F
GHS06
Toxic
- Acute toxicity (oral, dermal, inhalation), categories 1, 2, 3
GHS09
Environmental hazard
- Acute hazards to the aquatic environment, category 1
- Chronic hazards to the aquatic environment, categories 1, 2
- Environmental toxicity, categories 1, 2
Safety & Transport Information
Highly toxic due to phosphide, which in presence of moisture emits phosphine. The phosphine may ignite spontaneously in air. Incandescent reaction with oxygen at 300°C. Incompatible with dichlorine oxide. When heated to decomposition it emits toxic fumes of POx. See also CALCIUM COMPOUNDS and PHOSPHIDES.
Risk Codes:
R15/29 - Contact with water liberates toxic, extremely flammable gases
R28 - Very toxic if swallowed
R50 - Very toxic to aquatic organisms
Safety Codes:
S22 - Do not breathe dust
S28 - After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
S36/37 - Wear suitable protective clothing and gloves
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
Hazard Symbols:
Dangerous fire risk; decomposed by water to phosphine, which is highly toxic and flammable. See Phosphine.
RID/ADR certification :
UN 1360 4.3 / PG 1
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Alternative Distributors of [Calcium phosphide]
Producers or manufacturers change the product range from time to time.
The following companies
have appeared as suppliers in the past / currently not verified
ABCR GmbH & Co. KG | Jinan Haohua Industry Co., Ltd. | Pfaltz & Bauer, Inc. | Xiamen Hisunny Chemical Co., Ltd. | Haihang Industry Co., Ltd.