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(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

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Formula: C36H52CoN2O2
CAS: 176763-62-5

Identification

Structural Formula
(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:
176763-62-5
EINECS:
Molecular Formula:
C36H52CoN2O2
MDL:
MFCD01631277
SMILES:
CC(C1=C/C(=C/N[C@H]2[C@@H](CCCC2)N/C=C/3C(=O)C(=CC(=C3)C(C)(C)C)C(C)(C)C)/C(=O)C(=C1)C(C)(C)C)(C)C.[Co]
Synonym:
(1r,2r)-(-)-n,n'-bis(3,5-di-t-butylsalicydene)-1,2-cyclohexanediaminocobalt(ii) ; (1r,2r)-(-)-1,2-cyclohexanediamino-n,n'-bis(3,5- di-t-butylsalicylidene)cobalt ; (1r,2r)-(-)-1,2-cyclohexanediamino-n,n'-bis(3,5- ; (r,r)-(-)-n,n'-bis(3,5-di-t-butylsalicyl id -ene)-1,2-cyclohexanediaminocobalt(ii ; (1r,2r)-(-)-n,n-bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(ii) ; (r,r)-(-)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) ; (1r,2r)-(-)-1,2-cyclohexanediamino-n,n'-bis(3,5-di-t-butylsalicylidene) cobalt(II) ; (1r,2r)-(-)-1,2-cyclohexanediamino-n n'-bis(3,5-di-t-butylsalicylidene)cobalt(ii) ; (r,r)-(-)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(ii) ; cyclohexanediaminonnbisditbutylsalicylidene


Description

A catalyst for the hydrolytic kinetic resolution of terminal epoxides and the enantioselective ring opening of meso epoxides.


Suppliers

Conscientia Industrial Co., Ltd (Zhejiang Conscientia Pharmaceutical)
CI56580226320
Shanghai Kangxin Chemical Co., LTD
SKC27880111520
BLD Pharmatech Ltd
BP1476044280
Chemlyte Solutions
CS1476044280
JieJie Group Co., Ltd.
JG1804054120
Feiming Chemical Limited.
FCL2050082000
Feiming Chemical Limited.
SFC007
Shanghai UCHEM Inc.
SU1558046740
Hangzhou Keying Chem Co., Ltd.
HKC2460098400
Carbone Scientific Co., Ltd.
CS2296068880
AK Scientific, Inc.
AS1558046740
Leap Chem Co., Ltd
LC1476044280
Santa Cruz Biotechnology, Inc.
250835
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Prices & Availability




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Properties for (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

Molecular Weight:
603.74 g·mol−1
Melting point:
>350 °C(lit.)
Physical Description:
orange to red-brown powder
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed
Safety Codes:
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
Hazard Symbols:
Xn
Hazard symbol Xn
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Alternative Distributors of [(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Jinan Great Chemical Co., Ltd. | Feiming Chemical Limited. | Atomole Scientific Co., Ltd.

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