Identification
(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
Molecular Formula:
C1 8 H2 8 N2 P2
SMILES:
CP(C1=NC2=CC=CC=C2N=C1P(C)C(C)(C)C)C(C)(C)C
Synonym:
(r,r)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline 97% ; (r,r)-(-)-2,3-bis(t-butylmethylphosphino)quinoxaline, min. 98% (r,r)-quinoxp* ; (2r,3r)-2,3-bis[(tert-butyl)(methyl)phosphino]quinoxaline ; (r,r)-(-)-2,3-bis(t-butylmethylphosphino)quinoxaline ; 2,3-bis((r)-tert-butyl(methyl)phosphino)quinoxaline ; (r,r)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline ; quinoxaline,2,3-bis[(r)-(1,1-dimethylethyl)methylphosphino]- ; (r) quinoxp ; 2,3-bis[(r)-(tert-butyl)(methyl)phosphino]quinoxaline ; (r) quinoxp(r)
Description
(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline is an efficient ligand exhibiting high levels of enantiocontrol in synthetic transformations ranging from metal-catalyzed 1,4-addition of arylboronic acids to asymmetric hydrogenation to alkylative ring opening.
Suppliers
Santa Cruz Biotechnology, Inc.
253342
CAS equal suppliers
(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline
Pharmacore Co., Limited
PL956828704
Prices & Availability
Data is processed
Properties
Safety & Transport
Alternative Distributors
Downloads
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Properties for (R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
Molecular Weight:
334.38 g·mol−1
Melting point:
100-104 °C
x
Hazard Statements
GHS03
Harmful
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, categories 2, 3
Eye irritation, category 2A
Skin sensitization, category 1
Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects
Not used
with the "skull and crossbones" pictogram
for skin or eye irritation if:
the "corrosion" pictogram also appears
the "health hazard" pictogram is used to indicate respiratory sensitization
Safety & Transport Information
Risk Codes:
R22 - Harmful if swallowedR36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Hazard Symbols:
Xn
RID/ADR certification :
UN2811 6.1/PG 3
x
Alternative Distributors of [(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline]
Producers or manufacturers change the product range from time to time.
Currently there are no other manufacturers known.