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(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline

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Formula: C18H28 N2 P2
CAS: 866081-62-1

Identification

Structural Formula
(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
CAS:
866081-62-1
EINECS:
Molecular Formula:
C18H28 N2 P2
MDL:
MFCD09265091
SMILES:
CP(C1=NC2=CC=CC=C2N=C1P(C)C(C)(C)C)C(C)(C)C
Synonym:
(r,r)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline 97% ; (r,r)-(-)-2,3-bis(t-butylmethylphosphino)quinoxaline, min. 98% (r,r)-quinoxp* ; (2r,3r)-2,3-bis[(tert-butyl)(methyl)phosphino]quinoxaline ; (r,r)-(-)-2,3-bis(t-butylmethylphosphino)quinoxaline ; 2,3-bis((r)-tert-butyl(methyl)phosphino)quinoxaline ; (r,r)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline ; quinoxaline,2,3-bis[(r)-(1,1-dimethylethyl)methylphosphino]- ; (r) quinoxp ; 2,3-bis[(r)-(tert-butyl)(methyl)phosphino]quinoxaline ; (r) quinoxp(r)


Description

(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline is an efficient ligand exhibiting high levels of enantiocontrol in synthetic transformations ranging from metal-catalyzed 1,4-addition of arylboronic acids to asymmetric hydrogenation to alkylative ring opening.


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Santa Cruz Biotechnology, Inc.
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CAS equal suppliers

(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline
Pharmacore Co., Limited
PL956828704

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Properties for (R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline

Molecular Weight:
334.38 g·mol−1
Melting point:
100-104 °C
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Hazard Symbols:
Xn
Hazard symbol Xn
RID/ADR certification :
UN2811 6.1/PG 3
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Alternative Distributors of [(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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Downloads

Mol File:
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MSDS:
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