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(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a3,4-a′]dinaphthalen-4-yl)methylamine

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Formula: C28H22NO2P
CAS: 490023-37-5
search Element: dinaphthalen methylamine cyclohepta phospha benzyl dioxa prime
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Identification

Structural Formula
(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a3,4-a′]dinaphthalen-4-yl)methylamine
CAS:
490023-37-5
EINECS:
Molecular Formula:
C28H22NO2P
MDL:
SMILES:
CN(CC1=CC=CC=C1)P1OC2=CC=C3C=CC=CC3=C2C2=C(O1)C=CC1=CC=CC=C21
Synonym:
n-benzyl-n-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine ; 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99% ; 3,4-a']dinaphthalen-4-yl)methylamine 97% ; (s)-(+)-benzyl(3,5-dioxa-4-phospha-cycl& ; (s)-(+)-benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a ; 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99% ; (11bs)-n-methyl-n-(phenylmethyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine ; (s)-(+)-benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)methylamine ; (+)-n-benzyl-n-methyl-dinaphtho[2,1-d:1',2']dioxaphosphepin-4-amine, (11bs) ; 3,4-a']dinaphthalen-4-yl)methylamine


Description

Phosphoramidite ligand used in a rhodium-catalyzed enantioselective 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds. Also used in asymmetric hydrogenation of N-acylated β-dehydroamino esters to enantiopure β-amino acid derivatives.


Suppliers

Santa Cruz Biotechnology, Inc.
253097
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CAS equal suppliers

N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Chemieliva Pharmaceutical Co., Ltd.
CP1491044730
N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Hangzhou MolCore BioPharmatech Co.,Ltd.
MC113454
(11bS)-N-benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
BLD Pharmatech Ltd
BP982829484
(11bS)-N-Methyl-N-(phenylmethyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Leap Chem Co., Ltd
LC1409442282
(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a′]dinaphthalen-4-yl)methylamine
Santa Cruz Biotechnology, Inc.
sc-253097

Prices & Availability




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Properties for (S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a3,4-a′]dinaphthalen-4-yl)methylamine

Molecular Weight:
435.45 g·mol−1
Melting point:
155-159 °C
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Safety & Transport Information

Risk Codes:
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
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Alternative Distributors of [(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a3,4-a′]dinaphthalen-4-yl)methylamine]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG

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