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Azobenzene

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Formula: C12H10N2
CAS: 103-33-3
search Element: azobenzene

Identification

Structural Formula
Azobenzene
CAS:
103-33-3
EINECS:
203-102-5
Molecular Formula:
C12H10N2
MDL:
MFCD00003022
SMILES:
C1=CC=C(C=C1)N=NC2=CC=CC=C2
Synonym:
azobenzen ; azofume ; nsc 2102 ; azobenze ; a 15073 ; azobenzol ; azobenzeen ; ent14,611 ; benzofume ; ent 14,611


Description

Azobenzene is a photosensitive chemical that can switch between the cis and trans formations upon the presence of light at differing wavelengths. Azobenzene can convert from trans to cis in the presence of ultraviolet light, or cis to trans in the presence of blue light of the visible spectrum. The use of such photosensitive properties has been to construct photoswitch tethered ligands to turn protein activity on and off. The compound has been used to drastically increase the extracellular or intracellular concentration of active molecules to study the mechanism of action of sympathetic and parasympathetic neuromediators.


Suppliers

Aozeal Certified Standards (AOCS), Inc.
A0100.00
Krada CPS Industry S.L
KCIS2201100
Sigma-Aldrich International GmbH
SI320960
Carbone Scientific Co., Ltd.
CS280840
Pharmacore Co., Limited
PL230690
CM Fine Chemicals
CFC170680
AK Scientific, Inc.
AS190570
Xingrui Industry Co., Limited
XIL2901160
Amadis Chemical Company Limited
ACCL3101550
Santa Cruz Biotechnology, Inc.
214563
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CAS equal suppliers

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Acros Organics BVBA
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Alfa (A Johnson Matthey Company)
A5121536
trans-Azobenzene
Haihang Industry Co., Ltd.
HI4161248
trans-Azobenzene
Merck Schuchardt OHG
MSO3201280
Diazene, diphenyl-
Angene International Limited
AGN-PC-0CQHWS
1,2-Diphenyldiazene
Leap Chem Co., Ltd
LC3421026

Prices & Availability




Data is processed


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Properties for Azobenzene

Molecular Weight:
182.22 g·mol−1
Density:
1.09 g/mL at 25 °C(lit.)
Melting point:
66 °C
Boiling point:
293 °C(lit.)
Flash point:
100 °C
Solubility:
Insoluble in water and soluble in alcohol, ether, benzene and glacial acetic acid.
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2
GHS09

GHS09
Environmental hazard
  • Acute hazards to the aquatic environment, category 1
  • Chronic hazards to the aquatic environment, categories 1, 2
  • Environmental toxicity, categories 1, 2

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R20/22 - Harmful by inhalation and if swallowed
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed
R38 - Irritating to skin
R39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
R45 - May cause cancer
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R48/22 - Harmful: danger of serious damage to health by prolonged exposure if swallowed
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 - Possible risk of impaired fertility
R65 - Harmful: may cause lung damage if swallowed
R67 - Vapours may cause drowsiness and dizziness
R68 - Possible risk of irreversible effects
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S29 - Do not empty into drains
S33 - Take precautionary measures against static discharges
S36/37 - Wear suitable protective clothing and gloves
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S53 - Avoid exposure - obtain special instructions before use
S60 - This material and its container must be disposed of as hazardous waste
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S7 - Keep container tightly closed
S9 - Keep container in a well-ventilated place
Hazard Classes:
6.1(b)
Hazard Symbols:
T, N, Xn, F
Hazard symbol T Hazard symbol N Hazard symbol F Hazard symbol Xn
Storage temperature :
2-8°C
RID/ADR certification :
UN 3077 9 / PG 3
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Alternative Distributors of [Azobenzene]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG | TCI Europe NV | East Chemical Industry Co., Ltd. | Jinan Haohua Industry Co., Ltd. | Pfaltz & Bauer, Inc. | Clearsynth Canada INC.

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Downloads

Mol File:
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MSDS:
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