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N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-4-methoxytrityl-L-lysine

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Formula: C41H40N2O5
CAS: 159857-60-0
search Element: fluorenylmethyloxycarbonyl methoxytrityl epsilon lysine alpha
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Identification

Structural Formula
N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-4-methoxytrityl-L-lysine
CAS:
159857-60-0
EINECS:
Molecular Formula:
C41H40N2O5
MDL:
MFCD00270542
Synonym:
L-Lysine, N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-N6-[(4-methoxyphenyl)diphenylm ethyl]-


Description

Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation. References: A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789. Solid phase strategies: Applications of 2-acetyl-4-nitroindane-1,3-dione as a selective protecting group for primary amines; B. Kellam, B. W. Bycroft, W. C. Chan and S. R. Chhabra; Tetrahedron 1998; 54: 6817-6832. doi:http://dx.doi.org/10.1016/S0040-4020(98)00365-2


Suppliers

Iris Biotech GmbH
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Alternative Distributors of [N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-4-methoxytrityl-L-lysine]

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ABCR GmbH & Co. KG

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