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N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl]-L-lysine

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Formula: C34H42N2O6
CAS: 204777-78-6
search Element: fluorenylmethyloxycarbonyl dioxocyclohex methylbutyl dimethyl epsilon ylidene lysine alpha
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Identification

Structural Formula
N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl]-L-lysine
CAS:
204777-78-6
EINECS:
Molecular Formula:
C34H42N2O6
MDL:
Synonym:
fmoc-n-epsilon-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-l-lysine ; fmoc-lys(ivdde)-oh ; fmoc-lysine(ivdde)-oh ; n-α-fmoc-n-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-l-lysine ; fmoc-lys(ivdde)-oh n-α-fmoc-n-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1 -ylidene)-3-methylbutyl-l-lysine ; n-alpha-(9-fluorenyl)methoxycarbonyl)-n-epsilon-[1-(4,4-dimethyl-2,6-dioxocyclohexylidene-3-methylbutyl]-l-lysine ; fmoc-l-lys(ivdde)-oh ; n-alpha-fmoc-n-epsilon-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-l-lysine ; fmoc-lys(ddiv)-oh ; fmoc-lys(ddiv)-ohfmoc-ly


Description

Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation. Reference: A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.


Suppliers

Iris Biotech GmbH
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Properties for N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl]-L-lysine

Molecular Weight:
574.71 g·mol−1
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Safety & Transport Information

Storage temperature :
2-8°C
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Alternative Distributors of [N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl]-L-lysine]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG | AOKBIO Co., Ltd. | Wanko Chemical Co., Ltd.

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