N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-benzyloxycarbonyl-L-lysine | CAS 86060-82-4

Element: fluorenylmethyloxycarbonyl benzyloxycarbonyl epsilon lysine alpha

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C-S » Chemicals » alpha-fluorenylmethyloxycarbonyl-epsilon-benzyloxycarbonyl-lysine-PX1831131

Identification

N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-benzyloxycarbonyl-L-lysine

CAS:

86060-82-4

EINECS:

Molecular Formula:

C₂₉H₃₀N₂O₆

MDL:

Synonym:

fmoc-lysine(z)-oh ; nepsilon-fmoc-nalpha ; fmoc-lys(z)-oh ; fmoc-lys(z) ; fmoc-lys(cbz)-oh ; fmoc-l-lys(cbz)-oh ; z-lysine(fmoc)-oh ; fmoc-lys(z)-oh ,98% ; fmoc-l-lys(z)-oh ; z-lys(fmoc)-oh

Description

Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation. Reference: A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.

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