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N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-aspartic acid beta-benzyl ester

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Formula: C26H23NO6
CAS: 86060-84-6
search Element: fluorenylmethyloxycarbonyl aspartic benzyl alpha ester acid beta
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Identification

Structural Formula
N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-aspartic acid beta-benzyl ester
CAS:
86060-84-6
EINECS:
Molecular Formula:
C26H23NO6
MDL:
MFCD00065630
Synonym:
4-benzyl n-fmoc-l-aspartate ; fmoc-l-asp(bzl)-oh ; fmox-asp(obzl)-oh ; fmoc-asp(obzl)-oh ; fmoc-l-aspartic acid b-benzylester ; fmoc-l-aspartic acid 4-benzyl ester ; fmoc-l-asp(obzl)-oh ; fmoc-aspartic acid(obzl)-oh ; fmoc-l-aspartic acid β-benzyl ester ; fmoc-l-aspartic acid beta-benzyl ester


Description

Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation. Reference: A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.


Suppliers

Iris Biotech GmbH
FAA1704
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Prices & Availability




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Properties for N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-aspartic acid beta-benzyl ester

Molecular Weight:
445.46 g·mol−1
Melting point:
120-130 °C
Physical Description:
white to light yellow crystal powde
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Safety & Transport Information

Safety Codes:
S22 - Do not breathe dust
S24/25 - Avoid contact with skin and eyes
Hazard Classes:
irritant
Storage temperature :
2-8°C
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Alternative Distributors of [N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-aspartic acid beta-benzyl ester]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

ABCR GmbH & Co. KG

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