N-alpha-t-Butyloxycarbonyl-N-epsilon-(2-chlorobenzyloxycarbonyl)-D-lysine | CAS 57096-11-4

Element: chlorobenzyloxycarbonyl butyloxycarbonyl epsilon lysine alpha

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C-S » Chemicals » alpha-butyloxycarbonyl-epsilon-chlorobenzyloxycarbonyl-lysine-PX1896495

Identification

N-alpha-t-Butyloxycarbonyl-N-epsilon-(2-chlorobenzyloxycarbonyl)-D-lysine

CAS:

57096-11-4

EINECS:

Molecular Formula:

C₁₉H₂₇ClN₂O₆

MDL:

MFCD00065585

Synonym:

boc-n-e-(2-chloro-z)-d-lysine ; boc-d-lys(cl-z) ; boc-d-lys(cl-z)-oh ; boc-d-lys(2-cl-cbz)-oh ; boc-d-lys(2-chloro-z)-oh ; boc-n'-(2-chloro-cbz ; boc-n'-(2-chloro-cbz)-d-lysine ; boc-d-lysine(2-chloro-z)-oh ; boc-l-lys(2-cl-cbz)-oh ; boc-d-lys(2-cl-z)-oh

Description

Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation. Reference: A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.

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Iris Biotech GmbH

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