N-alpha-t-Butyloxycarbonyl-beta-(2,4,6-trimethoxybenzylthio)-L-aspartic acid beta-t-butyl ester

Element: trimethoxybenzylthio butyloxycarbonyl aspartic alpha butyl ester acid beta beta

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C-S » Chemicals » alpha-butyloxycarbonyl-beta-trimethoxybenzylthio-aspartic-acid-beta-butyl-ester-PX2567280

Identification

N-alpha-t-Butyloxycarbonyl-beta-(2,4,6-trimethoxybenzylthio)-L-aspartic acid beta-t-butyl ester

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Description

This building block can be used for native chemical ligation at the position of Asp. After SàN acyl shift followed by desulfurization a peptide conjugate will yield bearing natural aspartic acid. Reference: Chemoselective Peptide Ligation-Desulfurization at Aspartate; Robert E. Thompson, Dr. Bun Chan, Prof. Leo Radom, Prof. Katrina A. Jolliffe, Prof. Richard J. Payne; Angew. Chem Int. Ed. 2013; 52(37): 9723. DOI: org/10.1002/anie.201304793

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