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N-alpha-t-Butyloxycarbonyl-D-aspartic acid beta-allyl ester

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Formula: C12H19NO7
CAS: 207120-58-9
search Element: butyloxycarbonyl aspartic allyl alpha ester acid beta
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Identification

Structural Formula
N-alpha-t-Butyloxycarbonyl-D-aspartic acid beta-allyl ester
CAS:
207120-58-9
EINECS:
Molecular Formula:
C12H19NO7
MDL:
MFCD01862278
Synonym:
d-aspartic acid, n-[(1,1-dimethylethoxy)carbonyl]-, 4-(2-propenyl) ester ; (r)-4-(allyloxy)-2-(tert-butoxycarbonylamino)-4-oxobutanoic acid ; ref dupl: boc-d-asp(oall)-oh


Description

Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation. Reference: A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.


Suppliers

Iris Biotech GmbH
BAA1025
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CAS equal suppliers

boc-d-aspartic acid-β-allylester
Indofine Chemical Co, Inc.
04-571
Boc-D-aspartic acid beta-allyl ester
Santa Cruz Biotechnology, Inc.
285132

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Properties for N-alpha-t-Butyloxycarbonyl-D-aspartic acid beta-allyl ester

Molecular Weight:
273.3 g·mol−1
Melting point:
46-48°C
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Alternative Distributors of [N-alpha-t-Butyloxycarbonyl-D-aspartic acid beta-allyl ester]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Chem-Impex International, Inc. | Iris Biotech GmbH | ChengDu KaiXin Technology Development Co., Ltd. | Suzhou Vosun Chemical Co.,Ltd.

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